2017年9月9日星期六

Polyester Resins

http://www.lanruichem.com/2017/09/09/polyester-resins.html

Polyester is often referred to as fiberglass – which is not technically accurate. Fiberglass is reinforcement and polyester is the resin.
Polyesters offer ease of handling, low cost, dimensional stability, as well as good mechanical, chemical-resistance and electrical properties. Polyester resins are the least expensive of the resin options, providing the most economical way to incorporate resin, filler and reinforcement. They are the primary resin matrix used in SMC (sheet molding compounds) and BMC (bulk molding compounds).
Thermoset Polyester resins are created by combining an alcohol like ethylene glycol with an organic acid like maleic anhydride.
The low viscosity and raw material cost of polyesters make the additions of filler and reinforcements a matter of practicality. In fact, filler is often called an extender, because it extends the value of the resin - reducing the cost of the final composite on as much as 50%.
It is possible to add or reduce strength with the reinforcement chosen. Other parts molded from polyesters have similar properties if the glass % reinforcements are similar. Polyester resin (neat) meaning without filler or reinforcements would be a very brittle resin and would never be used without fillers or reinforcements. "Buttons" are made from Polyester resins but do have fillers and pigments, just no reinforcement as one example of a non-reinforced product.

Best Processes

Open molding, SMC/BMC, LCM and RTM. The best process for your product is a function of your tooling budget, part specification (such as dimensional tolerance and physical properties) and production volume.

Reinforcements

Typically glass

Special Design Considerations

MFG’s dedicated design experts are available to help with your product design. MFG’s Technical Design Guide for FRP Composite Products and Parts provides in-depth information for product designers. You can download it on the bottom of this page.

Technical Details

A wide range of surface qualities are possible to satisfy different application needs, from a cosmetically beautiful Class A automotive/truck body panel to a rugged underground utility box.  Polyester formulations offer tremendous flexibility.
Physical properties are easy to tailor, driven primarily by the amount of glass reinforcement used. Fillers are easy to incorporate in polyesters and commonly used as resin extenders to meet design and cost targets.
Properties can be formulated for your product specification targets. Typical SMC properties with standard 28% glass reinforcement result in 12,000psi tensile strength and 25,000psi flexural strength.  Strength-weight ratio is very good and because of its low density (from 1.70 grams/cc formulated) it often replaces metallic parts that are close to five times heavier.
As an example, the modulus (stiffness) for a typical SMC can exceed 1.5MMpsi. Polyester resins have a normal viscosity of about 700 when cut in styrene (the standard monomer). We can tailor a custom formula to meet your specific design requirements.

Cost Considerations

Polyesters offer the lowest cost option for traditional fiberglass parts and can be used with a variety of tooling and processes.
keywords:Polyester Resins Introduction,Polyester Resins manufacturer,Polyester Resins factory,Polyester Resins supplier,Polyester Resins producer
Shandong  Lanrui Chemical Co.,Ltd
http://www.lanruichem.com
Contacts:Mr Lee
whatsapp & Phone:86-18706669360
Tel:86-546-8081277
86-400-807-0021
E-mail:lanruichem@gmail.com

WHAT IS THE DIFFERENCE BETWEEN EPOXY AND POLYESTER RESIN?

http://www.lanruichem.com/2017/09/09/what-is-the-difference-between-epoxy-and-polyester-resin.html

When you begin to compare the many forms and variations of epoxies, glues, and resins available today, the results may leave you scratching your head. One question often leads to another. The chemistry behind epoxy and the varying formulas of glue has come quite a long way over the years, and can be a bit intricate. So what is the difference between each product? Let’s find out.

COMMON QUESTION

Here is a simple question that we often encounter from DIY folks who find the need to make product choices:
“What is the difference between your PC- Epoxy products and the polyester resins found online or in hardware stores?”
Good question!
Epoxies and resins are adhesives commonly used in home, automobile, aircraft, and boat building repairs. They are also gaining ground as go-to DIY craft and jewelry materials. But, there are several key differences between epoxies and resins.

KEY DIFFERENCES BETWEEN EPOXIES AND RESINS

1. Bonding Strength
Epoxy is known for its higher bonding capabilities overall. An epoxy’s relative strength can hold up to 2,000 lbs. per square inch, while a polyester resin can hold less than 500 lbs. per square inch.
2. Resistance to Wear
Epoxy is more resistant to wearing, cracking and peeling, and corrosion or damage from chemical or environmental degradation. Polyester is more fragile and useful for temporary fixes, or low-stress use.
3. Cost Comparison
Epoxy is generally more expensive than resin, due to its strength and formulation requirements. Resin is more popular for craft and jewelry making,due to its lower cost. Remember, however, that you get what you pay for.
4. Resistance to Moisture
Epoxy is very moisture resistant, and certain formulations can even be applied underwater.  Polyester resin has minor resistance to moisture, is considered water-permeable, and can fracture easily.
5. Cure Time
Although cure times vary for both epoxy and resin, depending on the formulation and temperature at use, resin generally has a faster cure time. This can be good or bad, depending on the speed with which you want to finish your project. Both products can be manipulated somewhat by raising or lowering the temperature before use. Certain epoxies are also formulated for use in extreme temperatures.
6. Odor
Polyester is far less pleasant to work with than epoxy. Although it sets up much faster, it has the reputation for stinking badly enough to burn your nose hairs out. Make sure to use proper ventilationwhen applying both epoxies and resins.
7. Shelf Life
There is no doubt about it – epoxy products have a much longer shelf life than resins do. As long as it hasn’t been mixed, epoxy can sit in a garage for several years (or more) without losing its potency. Resin is much more fragile over time.
If you have additional questions on this topic, please contact us!
keywords:Polyester Resins Introduction,Polyester Resins manufacturer,Polyester Resins factory,Polyester Resins supplier,Polyester Resins producer
Shandong  Lanrui Chemical Co.,Ltd
http://www.lanruichem.com
Contacts:Mr Lee
whatsapp & Phone:86-18706669360
Tel:86-546-8081277
86-400-807-0021
E-mail:lanruichem@gmail.com

Polyester Resins Introduction

Polyester Resins Introduction

Polyester resins are the most widely used resin systems, particularly in the marine industry. By far the majority of dinghies, yachts and workboats built in composites make use of this resin system.
Polyester resins such as these are of the 'unsaturated' type. Unsaturated polyester resin is a thermoset, capable of being cured from a liquid or solid state when subject to the right conditions. It is usual to refer to unsaturated polyester resins as 'polyester resins', or simply as 'polyesters'. There is a whole range of polyesters made from different acids, glycols and monomers, all having varying properties.
There are two principle types of polyester resin used as standard laminating systems in the composites industry. Orthophthalic polyester resin is the standard economic resin used by many people. Isophthalic polyester resin is now becoming the preferred material in industries such as marine where its superior water resistance is desirable.
The figure below shows the idealised chemical structure of a typical polyester. Note the positions of the ester groups (CO - O - C) and the reactive sites (C* = C*) within the molecular chain.
Most polyester resins are viscous, pale coloured liquids consisting of a solution of a polyester in a monomer which is usually styrene. The addition of styrene in amounts of up to 50% helps to make the resin easier to handle by reducing its viscosity. The styrene also performs the vital function of enabling the resin to cure from a liquid to a solid by 'cross-linking' the molecular chains of the polyester, without the evolution of any by-products. These resins can therefore be moulded without the use of pressure and are called 'contact' or 'low pressure' resins. Polyester resins have a limited storage life as they will set or 'gel' on their own over a long period of time. Often small quantities of inhibitor are added during the resin manufacture to slow this gelling action.
For use in moulding, a polyester resin requires the addition of several ancillary products. These products are generally:
Catalyst
Accelerator
Additives: Thixotropic; Pigment; Filler; Chemical/fire resistance
A manufacturer may supply the resin in its basic form or with any of the above additives already included. Resins can be formulated to the moulder's requirements ready simply for the addition of the catalyst prior to moulding. As has been mentioned, given enough time an unsaturated polyester resin will set by itself. This rate of polymerisation is too slow for practical purposes and therefore catalysts and accelerators are used to achieve the polymerisation of the resin within a practical time period. Catalysts are added to the resin system shortly before use to initiate the polymerisation reaction. The catalyst does not take part in the chemical reaction but simply activates the process. An accelerator is added to the catalysed resin to enable the reaction to proceed at workshop temperature and/or at a greater rate. Since accelerators have little influence on the resin in the absence of a catalyst they are sometimes added to the resin by the polyester manufacturer to create a 'pre-accelerated' resin.
The molecular chains of the polyester can be represented as follows, where 'B' indicates the reactive sites in the molecule.
With the addition of styrene 'S ', and in the presence of a catalyst, the styrene cross-links the polymer chains at each of the reactive sites to form a highly complex three-dimensional network as follows:
The polyester resin is then said to be 'cured'. It is now a chemically resistant (and usually) hard solid. The cross-linking or curing process is called 'polymerisation'. It is a non-reversible chemical reaction. The 'side-by-side' nature of this cross-linking of the molecular chains tends to means that polyester laminates suffer from brittleness when shock loadings are applied.
Great care is needed in the preparation of the resin mix prior to moulding. The resin and any additives must be carefully stirred to disperse all the components evenly before the catalyst is added. This stirring must be thorough and careful as any air introduced into the resin mix affects the quality of the final moulding. This is especially so when laminating with layers of reinforcing materials as air bubbles can be formed within the resultant laminate which can weaken the structure. It is also important to add the accelerator and catalyst in carefully measured amounts to control the polymerisation reaction to give the best material properties. Too much catalyst will cause too rapid a gelation time, whereas too little catalyst will result in under-cure.
Colouring of the resin mix can be carried out with pigments. The choice of a suitable pigment material, even though only added at about 3% resin weight, must be carefully considered as it is easy to affect the curing reaction and degrade the final laminate by use of unsuitable pigments.
Filler materials are used extensively with polyester resins for a variety of reasons including:
To reduce the cost of the moulding
To facilitate the moulding process
To impart specific properties to the moulding
Fillers are often added in quantities up to 50% of the resin weight although such addition levels will affect the flexural and tensile strength of the laminate. The use of fillers can be beneficial in the laminating or casting of thick components where otherwise considerable exothermic heating can occur. Addition of certain fillers can also contribute to increasing the fire-resistance of the laminate.
keywords:Polyester Resins Introduction,Polyester Resins manufacturer,Polyester Resins factory,Polyester Resins supplier,Polyester Resins producer
Shandong  Lanrui Chemical Co.,Ltd
http://www.lanruichem.com
Contacts:Mr Lee
whatsapp & Phone:86-18706669360
Tel:86-546-8081277
86-400-807-0021
E-mail:lanruichem@gmail.com

2017年9月8日星期五

China Polyester Resin factory LR-9035 Hybrid Solid Polyester Resin China Polyester Resin manufacturer


It is a carboxyl saturated polyester resin, to be used together with epoxy resin, Primid XL-552/T105, TGIC
To produce hybrid and pure polyester powder coatings.
Potential Applications:
1, high gloss, good flow effect, wonderful mechanical properties, pretty decorative effects,
Excellent yellowing resistance and marked exterior durability.
2, It is most suitable to making low-gloss or semi-gloss powder coatings, high gloss powder coating.
3, It also has the functions of salt and alkali resistance, humidity and heat resistance and of acid durability,
Packing & storage:
1, 25KG in kraft paper bag;
2, In a ventilative, dry and clean place under 30degree, its shelf life is one year.
IndexLR9035
AppearanceLight yellow & clear flakes
Acid value (mgKOH/g)30-38
Softening point (degree)(Ring & Ball Method)105-120℃
Glass Transition Temperature (degree)≥60℃
China Polyester Resin factory LR-9035 Hybrid Solid Polyester Resin China Polyester Resin manufacturer
keywords:LR-9035 Hybrid Solid Polyester Resin,China Polyester Resin manufacturer,China Polyester Resin supplier,Polyester Resin MSDS,Polyester Resin TDS,Polyester Resin COA
Shandong  Lanrui Chemical Co.,Ltd
http://www.lanruichem.com
Contacts:Mr Lee
whatsapp & Phone:86-18706669360
Tel:86-546-8081277
86-400-807-0021
E-mail:lanruichem@gmail.com

China Polyester Resin factory LR-6040 Hybrid Solid Polyester Resin China Polyester Resin manufacturer

It is a carboxyl saturated polyester resin, to be used together with epoxy resin, Primid XL-552/T105, TGIC
To produce hybrid and pure polyester powder coatings.
Potential Applications:
1, high gloss, good flow effect, wonderful mechanical properties, pretty decorative effects,
Excellent yellowing resistance and marked exterior durability.
2, It is most suitable to making low-gloss or semi-gloss powder coatings, high gloss powder coating.
3, It also has the functions of salt and alkali resistance, humidity and heat resistance and of acid durability,
Packing & storage:
1, 25KG in kraft paper bag;
2, In a ventilative, dry and clean place under 30degree, its shelf life is one year.
IndexLR6040
AppearanceLight yellow & clear flakes
Acid value (mgKOH/g)45-55
Softening point (degree)(Ring & Ball Method)100-115℃
Glass Transition Temperature (degree)≥50℃


China Polyester Resin factory LR-6040 Hybrid Solid Polyester Resin China Polyester Resin manufacturer
keywords:LR-6040 Hybrid Solid Polyester Resin,China Polyester Resin manufacturer,China Polyester Resin supplier,Polyester Resin MSDS,Polyester Resin TDS,Polyester Resin COA
Shandong  Lanrui Chemical Co.,Ltd
http://www.lanruichem.com
Contacts:Mr Lee
whatsapp & Phone:86-18706669360
Tel:86-546-8081277
86-400-807-0021
E-mail:lanruichem@gmail.com

China Polyester Resin factory LR-5050 Hybrid Solid Polyester Resin China Polyester Resin manufacture

It is a carboxyl saturated polyester resin, to be used together with epoxy resin, Primid XL-552/T105, TGIC
To produce hybrid and pure polyester powder coatings.
Potential Applications:
1, high gloss, good flow effect, wonderful mechanical properties, pretty decorative effects,
Excellent yellowing resistance and marked exterior durability.
2, It is most suitable to making low-gloss or semi-gloss powder coatings, high gloss powder coating.
3, It also has the functions of salt and alkali resistance, humidity and heat resistance and of acid durability,
Packing & storage:
1, 25KG in kraft paper bag;
2, In a ventilative, dry and clean place under 30degree, its shelf life is one year.
IndexLR5050
AppearanceLight yellow & clear flakes
Acid value (mgKOH/g)70-80
Softening point (degree)(Ring & Ball Method)100-115℃
Glass Transition Temperature (degree)
≥50℃


LR-5050 Hybrid Solid Polyester Resin
keywords:China Polyester Resin factory,LR-5050 Hybrid Solid Polyester Resin,China Polyester Resin manufacturer,High quality Polyester Resin,China Polyester Resin supplier

Shandong  Lanrui Chemical Co.,Ltd
http://www.lanruichem.com
Contacts:Mr Lee
whatsapp & Phone:86-18706669360
Tel:86-546-8081277
86-400-807-0021
E-mail:lanruichem@gmail.com